Preconcentration procedures for trace cadmium determination in natural aqueous systems prior to zeeman etaas

Čundeva, Katarina and Stafilov, Trajche and Pavlovska, Gorica and Karadjova, Irina and Arpadjan, Sonja (2003) Preconcentration procedures for trace cadmium determination in natural aqueous systems prior to zeeman etaas. International Journal of Environmental Analytical Chemistry, 83 (12). pp. 1009-1019. ISSN https://doi.org/10.1080/03067310310001621051

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Abstract

Nanotrace Cd determination in natural waters using two new flotation collectors, lead(II) heptyldithiocarbamate, Pb(HpDTC)2, and cobalt(III) heptyldithiocarbamate, Co(HpDTC)3, are presented. The optimization of the most important experimental parameters for flotation is given. Zeeman electrothermal atomic absorption spectrometry (ZETAAS) is used as an instrumental technique for Cd measurement. The results are compared with those obtained by other preconcentration procedures as independent methods. The limit of detection of ZETAAS using Pb(HpDTC)2 as collector is 4.8 ng/L, while using Co(HpDTC)3 it is 3.0 ng/L.

Item Type: Article
Subjects: Scientific Fields (Frascati) > Engineering and Technology > Chemical engineering
Scientific Fields (Frascati) > Natural sciences > Chemical sciences
Scientific Fields (Frascati) > Engineering and Technology > Environmental engineering
Scientific Fields (Frascati) > Engineering and Technology > Other engineering and technologies
Divisions: Faculty of Technology and Technical Sciences
Depositing User: Prof. d-r. Gorica Pavlovska
Date Deposited: 04 Apr 2023 08:40
Last Modified: 04 Apr 2023 08:40
URI: https://eprints.uklo.edu.mk/id/eprint/7940

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