Electrothermal Atomic Absorption Spectrometric Determination of Nickel after its Flotation Enrichment by Iron(III) Hexamethylenedithiocarbamate

Stafilov, Trajche and Pavlovska, Gorica and Čundeva, Katarina (2000) Electrothermal Atomic Absorption Spectrometric Determination of Nickel after its Flotation Enrichment by Iron(III) Hexamethylenedithiocarbamate. Turkish Journal of Chemistry, 24 (4). pp. 303-310.

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Abstract

Abstract. Nanogram quantities of nickel were removed from 1 L samples of dilute aqueous solutions by coflotation. A mixture of hydrated iron(III) oxide (Fe_2O_3\( \cdot \)xH_2O) and iron(III) hexamethylene-dithiocarbamate (Fe(HMDTC)_3) served as collectors. After flotation separation from the mother liquor, the solid sublate containing nickel traces was dissolved and the analyte was determined by electrothermal atomic absorption spectrometry (ETAAS). All important parameters necessary for the successful collection of nickel were checked. The results of nickel ETAAS analysis in tap and spring waters were compared with inductively coupled plasma-atomic emis-sion spectrometric measurements (ICP-AES). The limit detection of nickel by the ETAAS method is 0.0078 ( \mu )g/L.

Item Type: Article
Subjects: Scientific Fields (Frascati) > Engineering and Technology > Chemical engineering
Scientific Fields (Frascati) > Natural sciences > Chemical sciences
Scientific Fields (Frascati) > Engineering and Technology > Environmental engineering
Scientific Fields (Frascati) > Engineering and Technology > Other engineering and technologies
Divisions: Faculty of Technology and Technical Sciences
Depositing User: Prof. d-r. Gorica Pavlovska
Date Deposited: 03 Apr 2023 12:34
Last Modified: 03 Apr 2023 12:34
URI: https://eprints.uklo.edu.mk/id/eprint/7925

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